Publication detail

Synthesis and Structure of NCN-Chelated Organobismuth(III) Bis-Pentasulfide

Authors: Dostál Libor | Jambor Roman | Erben Milan | Růžička Aleš

Year: 2012

Type of publication: článek v odborném periodiku

Name of source: Zeitschrift für anorganische und allgemeine Chemie

Publisher name: Wiley-VCH

Place: Weinheim

Page from-to: 614-616

Titles:

Language	Name	Abstract	Keywords
cze	Syntéza NCN-chelatovaného bismutitého pentasulfidu	Byla popsána syntéza NCN-chelatovaného bismutitého pentasulfidu. Byla studvána jeho struktura	poloměry kovalentní vazby, kineticky stabilizovaný silanthion obsahující cyklické polysulfidy, síra, komplexy, prvky, chalkogenidů, reaktivita, germanium, sulfidy, vizmut, Sulfur, cheláty, hlavní skupiny prvků, kruhová expanze, X-ray difrakce
eng	Synthesis and Structure of NCN-Chelated Organobismuth(III) Bis-Pentasulfide	Organobismuth(III) sulfide (1) containing the NCN pincer type chelating ligand L {L = [2, 6-(CH2NMe2)2C6H3]} reacts with one molar equivalent of elemental sulfur to give the unprecedented cyclic bis-pentasulfide LBi(mu-S5)2BiL (2) with the central twelve-membered ring Bi2S10. Compound 2 was obtained as stable orange crystals and was characterized by the help of elemental analysis, X-ray diffraction technique, IR, and Raman spectroscopy.	bond covalent radii; kinetically stabilized silanethione; containing cyclic polysulfides; complexes; chalcogenides; reactivity; germanium; sulfides; bismuth; sulfur; chelates; ring expansion; X-ray diffraction

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