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Reversible CO2 fixation by intramolecularly coordinated diorganotin(IV)oxides
Authors: Mairychová Barbora | Dostál Libor | Růžička Aleš | Beneš Ludvík | Jambor Roman
Year: 2012
Type of publication: článek v odborném periodiku
Name of source: Journal of Organometallic Chemistry
Page from-to: 1-4
Titles:
Language Name Abstract Keywords
cze CO2 fixace pomocí organociničitých oxidů. Byla studována reverzibilní fixace oxidu uhličitého pomocí organocíničitých oxidů. Oraganocín (IV), fixace CO2, uhličitany
eng Reversible CO2 fixation by intramolecularly coordinated diorganotin(IV)oxides The intramolecularly coordinated organotin(IV) oxides [L(Ph)Sn(μ-O)]2 (1) and [L(Bu)Sn(μ-O)]2 (2) readily absorb CO2 yielding molecular organotin(IV) carbonates L(Ph)SnCO3 (3) and L(Bu)SnCO3 (4) with terminally bonded the carbonate moiety. The easy desorption and reversible CO2 fixation was achieved. Organotin(IV); CO2 fixation; Carbonate