Publication detail

Monomeric organoantimony(III) sulphide and selenide with terminal Sb-E bond (E = S, Se). Synthesis, structure and theoretical consideration

Year: 2012

Type of publication: článek v odborném periodiku

Name of source: Dalton Transactions

Publisher name: Royal Society of Chemistry

Place: Cambridge

Page from-to: 5140-5143

Titles:

Language	Name	Abstract	Keywords
cze	Monomerní organoantimonitý sulfid a selenid	NCN chelatované monomerní chalkogenidy LSbE (E = S (1), Se (2), L = 2,6-bis[N-(2',6'-dimethylphenyl)ketimino]phenyl) byly připraveny a obsahují terminální vazbu Sb-Se a Sb-S.	hlavní sklupina prvků, kovalentní poloměr, jednoduchá vazba, DIPNICTENES, ligandy
eng	Monomeric organoantimony(III) sulphide and selenide with terminal Sb-E bond (E = S, Se). Synthesis, structure and theoretical consideration	NCN chelated monomeric chalcogenides, LSbE (E = S (1), Se (2), L = 2,6-bis[N-(2',6'-dimethylphenyl)ketimino]phenyl), were synthesized and characterized with the help of elemental analysis, NMR spectroscopy and single-crystal X-ray diffraction analyses. The terminal Sb-E (E = S, Se) bonds in 1 and 2 were subjected to theoretical investigation and the results are compared with the hypothetical molecules, PhSb=E (E = S, Se, Te), and earlier reported analogues.	MAIN-GROUP ELEMENTS; COVALENT RADII; SINGLE-BOND; DIPNICTENES; LIGANDS

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