Publication detail

Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: high-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14)

Year: 2012

Type of publication: článek v odborném periodiku

Name of source: Chemistry - A European Journal

Publisher name: Wiley-VCH

Place: Weinheim

Page from-to: 13156-13159

Titles:

Language	Name	Abstract	Keywords
cze	Skeletální alkylkarbonační (SAC) reakce jako jednoduchý model pro klastr-karbonovou inserci a cross-coupling: vysoký výtěžek substitovaných trikarbollidů z 6,9-dikarba-arachno-dekaboranu(14)	Byla vyvinuta jednoduchá cesta s vysokým výtěžkem k přípravě série trikarbollidenových sloučenin 8-R-nido-7,8,9-C3B8H11 a [8-R-nido-7,8,9-C3B8H10]− (např. R=Me, Ph, a 1-nafthyl). Metoda je založena na novém typu C-inzerce cross-couplingu skrz skeletální alkylkarbonační (SAC) reakce mezi acyl chloridy (RCOCl) a arachno-6,9-C2B8H14 karboranem.	acyl chloridy; borany; karborany; cross-coupling; syntetické metody
eng	Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: high-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14)	A simple and high-yield route to a series of tricarbollide compounds 8-R-nido-7,8,9-C3B8H11 and [8-R-nido-7,8,9-C3B8H10]− (exemplified by R=Me, Ph, and 1-naphthyl) was developed. The method is based on a new type of C-insertion cross-coupling through skeletal alkylcarbonation (SAC) reactions between acyl chlorides (RCOCl) and the arachno-6,9-C2B8H14 carborane.	acyl chlorides; boranes; carboranes; cross-coupling; synthetic methods

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