Publication detail

The chemistry of pincer complexes of 13 - 15 main group elements

Authors: Dostál Libor | Jambor Roman

Year: 2013

Type of publication: článek v odborném periodiku

Name of source: Topics in Organometallic Chemistry

Publisher name: Springer

Place: Berlin

Page from-to: 175-202

Titles:

Language	Name	Abstract	Keywords
cze	Chemie Y,C,Y-chelatujích komplexů prvků 13-15 skupiny	Nedávné studie chemie prvků 13 ? 15 skupiny obsahující Y,C,Y-koordinující ligandy jsou shrnuty. Tato kapitola se zabýva chemií težších prvků 13 skupiny (Ga, In Tl), 14 skupiny (Ge, Sn, Pb), převážne v oxidačních stavech +II a +I a také prvků 15 skupiny (As, Sb, Bi).	Chemie;Y,C,Y-chelatují ligandy;prvky 13-15 skupiny
eng	The chemistry of pincer complexes of 13 - 15 main group elements	Recent achievements in the chemistry of selected group 13 ? 15 elements con-taining pincer type coordinating ligands are summarized. This chapter covers chemistry of heavier elements Ga, In Tl form the group 13, Ge, Sn, Pb ? especially low valent compounds with formal oxidation state +II or +I and their reactivity from the group 14 and As, Sb, Bi from the group 15. Only the classical pincer type ligands containing nitrogen or oxygen atoms as in-built donor functionalities are considered i.e. 2,6-(R2NCH2)2C6H3 (LN1), 2,6-(ArN=C(CH3))2C6H3 (LN2), 2,6-(ROCH2)C6H3 (LO1, 2, R = Me, t-Bu), 2-(Me2NCH2)-6-(ROCH2)C6H3 (LNO1,2, R = Me, t-Bu), 2,6-((RO)2P(O))2-4-(t-Bu)C6H3 (LPO). The influence of the present pincer ligands on the structures of the compounds as well as their key role in the stabilization of these compounds is discussed.	Organometallic;Pincer Complexes;13-15 Main Group Elements

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