Publication detail

Determination of dithiocarbamate fungicide using copper solid amalgam electrode

Authors: Nováková Kateřina | Navrátil Tomáš | Jaklová Dytrtová Jana | Chýlková Jaromíra

Year: 2012

Type of publication: článek ve sborníku

Name of source: International Conference Proceedings of PSCR

Publisher name: Planetary Scientific Research Center

Place: Singapore

Page from-to: 43-46

Titles:

Language	Name	Abstract	Keywords
cze	Stanovení fungicidu pomocí měděné pevné amalgámové elektrody	Bylo studováno voltametrické chování Thiramu s použitím rtuťové modifikované pevné amalgámové elektrody.	thiram; pevná amalgámová elektroda; voltametrie
eng	Determination of dithiocarbamate fungicide using copper solid amalgam electrode	With mercury modified copper solid amalgam electrode (inner diameter 1.5 mm), the voltammetric behavior of thiram was studied. Differential pulse voltammetry (DPV) and direct current voltammetry (DCV) were utilized for this purpose. The reaction mechanism was investigated using DCV and elimination voltammetry with linear scan (EVLS). The optimum conditions for DPV determination of thiram were found in Britton-Robinson (BR) buffer of pH = 5, initial potential Ein = +100 mV and accumulation potential Eacc = -200 mV vs. Ag/AgCl/3M KCl, scan rate 20 mV.s-1. Applying prolonged accumulation time (100 s), the limit of detection 3×10-9 mol.L-1 was reached.	Thiram; Cooper, Solid amalgam electrode; Voltammetry

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