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New MOF based on lithium tetrahydrofuran-2,3,4,5-tetracarboxylate: Its structure and conductivity behavior
Authors: Zima Vítězslav | Patil Deepak | Raja D.S. | Chang T.G. | Lin Ch.H. | Shimakawa Koichi | Wágner Tomáš
Year: 2014
Type of publication: článek v odborném periodiku
Name of source: Journal of Solid State Chemistry
Publisher name: Academic Press (Elsevier)
Page from-to: 150-158
Titles:
Language Name Abstract Keywords
cze Nová součenina typu MOF na bázi tetrahydrofuran-2,3,4,5-tetrakarboxylátu lithia: její struktura a vodivostní chování Nová MOF sloučenina, [Li6(HTFTA)2(H2O)3]•3H2O (LiTFTA, H4TFTA je tetrahydrofuran-2,3,4,5-tetrakarboxylová kyselina), byla syntetizován za solvothermálních podmínek a její struktura byla stanovena. Protonová vodivost této sloučeniny s ohledem na teplotu a relativní vlhkost vzduchu byla analyzována naší nově vyvinutou metodou analýzy dat, tzv. random-walk. metal-organic framework; lithium; karboxylát
eng New MOF based on lithium tetrahydrofuran-2,3,4,5-tetracarboxylate: Its structure and conductivity behavior A novel metal–organic framework, [Li6(HTFTA)2(H2O)3]•3H2O (LiTFTA, H4TFTA is tetrahydrofuran-2,3,4,5-tetracarboxylic acid), has been synthesized under solvothermal conditions and its structure was determined by single-crystal X-ray diffraction studies. The proton conductivity behavior of this compound with respect to temperature and relative humidity was analyzed by our newly developed impedance data analysis method called a random-walk approach. metal-organic framework; lithium; carboxylate