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Organization and intramolecular charge-transfer enhancement in tripodal tris[(pyridine-4-yl)-phenyl]amine push-pull molecules by intercalation into layered materials bearing acidic functionalities.
Year: 2014
Type of publication: článek v odborném periodiku
Name of source: Dalton Transactions
Publisher name: Royal Society of Chemistry
Place: Cambridge
Page from-to: 10462-10470
Titles:
Language Name Abstract Keywords
cze Uspořádání a nárůst intramolekulárního přenosu náboje v tripodálních push-pull molekulách tris[(pyridin-4-yl)-fenyl]aminu po jejich interkalaci do vrstevnatých materiálů obsahujících kyselé funkční skupiny Interkalace tripodálních molekul tris[(pyridin-4-yl)-fenyl]aminu do hydrogenfosforečnanu a 4-sulfofenylfosfonátu zirkoničitého vede k jejich uspořádání v mezivrstvém prostoru hostitelů. Jak vyplývá z UV-vis a IČ spekter, hostěné molekuly jsou v interkalátech přítomny jak v protonované, tak v neprotonované formě. tripodal push-pull molekuly; interkalace; hydrogenfosforečnan zirkoničitý
eng Organization and intramolecular charge-transfer enhancement in tripodal tris[(pyridine-4-yl)-phenyl]amine push-pull molecules by intercalation into layered materials bearing acidic functionalities. Intercalation of tripodal molecules of tris[(pyridine-4-yl)-phenyl]amine into zirconium phosphate and zirconium 4-sulfophenylphosphonate leads to their organization in a layered system of the hosts. It follows from the UV-Vis and IR spectra that guest is present in both intercalates in an equilibrium of protonated and non-protonated forms. tripodal push-pull molecules; intercalation; zirconium hydrogenphosphate

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