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Non-isothermal crystallization kinetics of As2Se3 glass studied by DSC
Year: 2014
Type of publication: článek v odborném periodiku
Name of source: Thermochimica Acta
Publisher name: Elsevier Science BV
Place: Amsterdam
Page from-to: 56-63
Titles:
Language Name Abstract Keywords
cze Neizotermní krystalizační kinetika As2Se3 skla studovaná pomocí DSC Krystalizace ve sklovitém As2Se3 byla studována za neizotermních podmínek pomocí DSC. Výsledky získané pro různé frakce prášků byly analyzovány a diskutovány. krystalizace; kinetika; DSC; As2Se3 sklo; nukleace
eng Non-isothermal crystallization kinetics of As2Se3 glass studied by DSC Differential scanning calorimetry was used to study crystallization behavior in As2Se3 glass under non-isothermal conditions. The effects of changing particle size and glass-forming conditions were investigated. Based on the results of complete kinetic analysis, the crystallization kinetics was described in terms of the Johnson-Mehl-Avrami (JMA) nucleation-growth model: values of apparent activation energy and the JMA kinetic exponent were determined for all studied samples. A new conception involving the influences of the number of mechanically induced defects and amount of strains and stresses arising from the melt-quench on crystallization kinetics was introduced. The fundamental idea utilized within this conception incorporates the crucial role of both these considered factors, where the increased number of mechanical defects and heterogeneities effectively increases the number of primary nucleation centers, while the stress-induced defects originating from the glass-forming procedure seem to act as a surrogate for the secondary nucleation process participating in the growth of crystalline spherulites. Based on this novel conception, all trends and differences observable for the current data as well as for the data available in the literature were explained. Crystallization kinetics; DSC; JMA model; As2Se3 glass; Nucleation

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