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Possibilities and limitations of the determination of zinc(II) at gallium film electrodes. An initial study
Authors: Verbickas Rolandas | Norkus Eugenijus | Švancara Ivan
Year: 2014
Type of publication: článek v odborném periodiku
Name of source: Chemija
Publisher name: Lithuanian Academy of Sciences
Place: Vilnius
Page from-to: 34-38
Titles:
Language Name Abstract Keywords
cze Možnosti stanovení zinku jako Zn(II) na galliových filmových elektrodách. Úvodní studie Příspěvek je věnován základní charakterizaci elektrod s povlakem filmu kovového gallia (GaFEs); tj. jejím elektroanalytickým vlastnostem a chování; a to v souvislosti s možností stanovení Zn(II) na úrovni ppm; resp. desetin ppm; ve vzorcích přírodních i upravovaných vod. Galliový film; skelný uhlík; uhlíková pasta; nosná elektroda; anodická stripping voltametrie; zinek; stanovení
eng Possibilities and limitations of the determination of zinc(II) at gallium film electrodes. An initial study In this paper, basic electroanalytical properties and behaviour of the gallium film-plated electrodes (GaFEs) are presented. Being prepared by electrodeposition and plating onto two different carbonaceous electrode substrates, the following experimental characterisation of the individual GaFEs has been focused on their possible employment in stripping voltammetry. The most satisfying performance and fairly low background currents were achieved in acetate buffer or diluted hydrochloric acid, when using the square-wave voltammetric mode. The electroanalytical performance of a method with GaFE has been tested on model determinations of Zn(II) ions with satisfactory results. gallium film(s); glassy carbon- and carbon paste electrode substrates; anodic stripping voltammetry; zinc; determination