University of PardubiceFaculty of Chemical Technology

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Novel complexes of dissymmetric amidinates.

Authors: Novotný Martin | Růžička Aleš | Padělková Zdeňka

Year: 2014

Type of publication: ostatní - přednáška nebo poster

Page from-to: nestránkováno

Titles:

Language	Name	Abstract	Keywords
eng	Novel complexes of dissymmetric amidinates.	Lithium amidinates, of general formula, are frequently studied compounds. Most amidinates are prepared by the reaction, but due to the lack of bis(carbodiimides), we decided to prepare required amidinates by addition reaction of N,N’-disubstitued lithium amid to highly polarized C-N triple bond of amino-carbonitrile moiety with subsequent migration of substituents among the nitrogen atoms. So far nobody prepared dissymetric bis-amidinates connected by amidinate carbon atom via ring or chain. Main idea was to prepare series of amidinates formed by reaction N-trimethylsilyl amide with carbodinitriles. Further details about preparation of selected and studied amidinates will be discussed.