Publication detail

Opening of boroxines by N,C,N-chelated antimony(III), bismuth(III) and tin(IV) compounds

Authors: Kořenková Monika | Mairychová Barbora | Jambor Roman | Růžičková Zdeňka | Dostál Libor

Year: 2014

Type of publication: článek v odborném periodiku

Name of source: Inorganic Chemistry Communications

Publisher name: Elsevier Science BV

Place: Amsterdam

Page from-to: 128-130

Titles:

Language	Name	Abstract	Keywords
cze	Otvírání boroxínů pomocí N,C,N-chelatovaných sloučenin Sb, Bi a Sn	N,C,N-koordinované Sb(III), Bi(III) a Sn (IV) sloučeniny otvírají boroxínové kruhy. Připravené sloučeniny byly připraveny pomocí NMR a X ray difrakce.	Otvírání; boroxínů; pomocí; N,C,N-chelatovaných; sloučenin
eng	Opening of boroxines by N,C,N-chelated antimony(III), bismuth(III) and tin(IV) compounds	N,C,N-intramolecularly coordinated antimony(III) and bismuth(III) oxides (LMO)(2) [where M=Sb (1), Bi (2)] and tin(IV) carbonate LSnPh(CO3) (3) [L is an abbreviation for (2,6-Me2NCH2)(2)C6H3] were shown to open six-membered boroxine rings R3B3O3 (R=Me or OMe) giving heteroboroxine compounds LM[OB(R)](2)O [where M=Sb and R=Me (4) or OMe (5); M=Bi and R=Me (6)] and LSn(Ph)[OB(R)](2)O [where R=Me (7) or OMe (8)]. Studied compounds were characterized by the help of multinuclear NMR spectroscopy and in the case of 4 and 7 by means of single-crystal X-ray diffraction analysis.	Antimony; Bismuth; Tin; Chelating ligands; Heteroboroxines

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