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Reactivity of Bis(organoamino)phosphanes with Aluminum(III) Compounds: Straightforward Access to Diiminophosphinates by Means of Hydrogen-Atom Migration - An Experimental and Theoretical Study
Authors: Vrána Jan | Jambor Roman | Růžička Aleš | Mercedes Alonso | Frank de Proft | Dostál Libor
Year: 2014
Type of publication: článek v odborném periodiku
Name of source: European Journal of Inorganic Chemistry
Publisher name: Wiley-VCH
Place: Weinheim
Page from-to: 5193-5203
Titles:
Language Name Abstract Keywords
cze Reaktivita iminofosfánů s hlinitými sloučeninami Reaktivita aminofosfánů PhP(NHR)(NHR′) a tBuP(NHDip)2 s Me3Al byla studována. Reaktivita; iminofosfány; hlinité sloučeniny
eng Reactivity of Bis(organoamino)phosphanes with Aluminum(III) Compounds: Straightforward Access to Diiminophosphinates by Means of Hydrogen-Atom Migration - An Experimental and Theoretical Study The reactivity of bis(organoamino)phosphanes PhP(NHR)(NHR′) (1a–1c, in which R, R′ = tBu for 1a; tBu, Dip for 1b; and Ph for 1c; Dip = C6H3–2,6-iPr2) and tBuP(NHDip)2 (1d) with Me3Al was investigated. Reactivity; Bisorganoaminophosphanes; AluminumIII Compounds; Diiminophosphinates