Publication detail

Deamination of N -> Sn-Coordinated Organotin(II) Hydroxide: Formation of a New C-O Covalent Bond

Authors: Dostál Libor | Růžička Aleš | Jambor Roman

Year: 2014

Type of publication: článek v odborném periodiku

Name of source: European Journal of Inorganic Chemistry

Publisher name: Wiley-VCH

Place: Weinheim

Page from-to: 5266-5270

Titles:

Language	Name	Abstract	Keywords
cze	Deaminace organocínatého hydroxidu: Tvorba nové kovalentní C-O vazby	Byla studována příprava a reaktivita organocínatého hydroxidu, která vedla k deaminační reakci za vzniku nové C-O kovalentní vazby	Deaminace; organocínatého; hydroxidu; Tvorba; nové; kovalentní; C-O; vazby
eng	Deamination of N -> Sn-Coordinated Organotin(II) Hydroxide: Formation of a New C-O Covalent Bond	The synthesis of the pentacarbonylchromium complex [{2,6-(Me2NCH2)(2)C6H3}(Cl) SnCr(CO)(5)] is reported. Starting with this compound, organotin(II) pentacarbonylchromium methoxide [{2,6-(Me2NCH2)(2)C6H3}(OMe)SnCr(CO)(5)] was prepared and used for the synthesis of dimeric N -> Sn intramolecularly coordinated organotin(II) pentacarbonylchromium hydroxide [{2,6-(Me2NCH2)(2)C6H3}Sn(mu-OH)Cr(CO)(5)](2) by easy hydrolytic protocol. In addition, acid-base-type reaction of this latter compound with HOTf provided unprecedented cyclization product [6-(Me2NCH2)-2,3-(C6H3CH2OSn)Cr-(CO)(5)](2). The cyclization process is accompanied by the formation of a new C-O covalent bond along with the elimination of Me2NH.	Deamination; Sn-Coordinated; OrganotinII; Hydroxide; Formation; New; C-O; Covalent; Bond

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