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Publication detail

Influence of the shape of optically active molecules bearing 4- pyridyl terminus on the properties of their intercalates.
Year: 2015
Type of publication: ostatní - přednáška nebo poster
Page from-to: nestránkováno
Titles:
Language Name Abstract Keywords
eng Influence of the shape of optically active molecules bearing 4- pyridyl terminus on the properties of their intercalates. In this contribution, we describe intercalation of three optically active molecules having one two or three pyridine-4-yl moieties into α-Zr(HPO4)2·H2O, γ-Ti(HPO4)2·2H2O and zirconium sulfophenyl-phosphonate. The influence of the number of protonable atoms in the molecule and its shape on the amount of the guest molecules intercalated, their arrangement and especially on optical properties of the intercalates is discussed. intercalation; layered phosphonates; layered phophates