Login for students

Login for employees

Publication detail

Improvement of the quadratic non-linear optical properties of pyrimidine chromophores by N-methylation and tungsten pentacarbonyl complexation
Authors: Achelle Sylvain | Kahlal Samia | Barsella Alberto | Saillard Jean-Yves | Che Xiaoyang | Vallet Julien | Bureš Filip | Caro Bertrand | Robin-le Guen Francoise
Year: 2015
Type of publication: článek v odborném periodiku
Name of source: Dyes and Pigments
Publisher name: Elsevier Science
Place: Oxford
Page from-to: 562-570
Titles:
Language Name Abstract Keywords
cze Zlepšení kvadratických nelineárně-optických vlastností pyridinových chromoforů prostřednictvím methylace a komplexace s pentakarbonylwolframem Byly syntetizovány dvě série látek: 4-(arylvinyl)-1-methylpyrimidiniové soli a pentacarbonylwolframové komplexy 4-(arylvinyl)pyrimidinů. Byly měřeny nelineárně-optické vlastnosti a studovány fotofyzikální vlastnosti a porovnávány s vlastnostmi odpovídajících 4-(arylvinyl)pyrimidinů. Bylo pozorováno zvýšení NLO odezvy po provedené methylaci pyrimidinového jádra nebo po jeho komplexaci s W(CO)5. pyrimidin; vnitřní přenos náboje; push-pull chromofory; komplexy pentakarbonylwolframu; nelineární optika
eng Improvement of the quadratic non-linear optical properties of pyrimidine chromophores by N-methylation and tungsten pentacarbonyl complexation In this contribution, we report the synthesis of two series of compounds: 4-(arylvinyl)-1-methylpyrimidinium derivatives and tungsten pentacarbonyl complexes of 4-(arylvinyl)pyrimidines. Their second order non-linear properties, measured by Electric-Field Induced Second Harmonic generation (EFISH) method, and their photophysical behavior were thoroughly investigated and compared to the corresponding 4-(arylvinyl) pyrimidines. A strong enhancement of the NLO response was observed upon methylation or complexation by W(CO)(5) of the pyrimidine ring. DFT theoretical calculations were performed to provide complementary insights on the structure-properties relationships in particular concerning the amplitude of the NLO response. Pyrimidine; Internal charge transfer; Push-pull chromophores; Tungsten pentacarbonyl complexes; Non-linear optics; Theoretical calculations

Departments

Other Parts

Map

en.mapy.cz

Services

Popular Links

© 2023 University of Pardubice, Studentská 95, 532 10 Pardubice 2
Phone: +420 466 036 111, 466 036 112, 466 036 113
Webmaster, RSS
Data box ID: f5vj9hu
Accessibility Statement
CC BY-NC-ND 4.0Creative CommonsAttributionNonCommercialNoDerivatives