Publication detail

Elektrochemická studie oxazaborinových chromoforů

Authors: Mikysek Tomáš | Josefík František | Vytřas Karel | Ludvik Jiri

Year: 2015

Type of publication: článek ve sborníku

Name of source: XXXV Moderní elektrochemické metody

Publisher name: BEST Servis

Place: Ústí nad Labem

Page from-to: 152-155

Titles:

Language	Name	Abstract	Keywords
cze	Elektrochemická studie oxazaborinových chromoforů	Tento příspěvek popisuje základní elektrochemickou studii série nově syntetizovaných chromoforů na bázi oxazaborinu.	oxazaborin; chromofor; cyklická voltametrie
eng	Electrochemical Study of Oxazaborine Chromophores	This contribution describes a basic electrochemical study of a series of newly synthesized chromophores based on the oxazaborine core. The attention was focused on determination of the first oxidation and the first reduction potentials, their difference and the relationship to the calculated highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energies. The oxidation is mostly a two-electron irreversible process, the first reduction is also irrevesible, but involving one-electron. For better understanding of the relationship between the structure and redox properties, the approach using sigma (para) constants of Hammett type was applied, the difference between E(ox) and E(red) was correlated with the HOMO-LUMO gap.	Oxazaborines; Chromophore; Cyclic voltammetry

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