Publication detail

Activation of Inorganic and Organic molecules by a Germylene Stabilized by a Boraguanidinate ligand

Authors: Böserle Jiří | Dostál Libor

Year: 2015

Type of publication: ostatní - přednáška nebo poster

Page from-to: nestránkováno

Titles:

Language	Name	Abstract	Keywords
eng	Activation of Inorganic and Organic molecules by a Germylene Stabilized by a Boraguanidinate ligand	The investigation dealing with reactivity of germylene 1 containing in its structure a boraguanidinate ligand will be presented. This type of dianionic N,N’-chelating ligands is derived from guanidinate ligands by a substitution a carbon atom by a boron atom and represents a relatively unexplored branch of organometallic chemistry. The electronic and steric properties of these ligands may be fine-tuned by the use of different substituents on the BN3 backbone. Another interesting property of these ligands is dianionic character which significantly affects their reactivity.2 Reactions of variety of substrates with compounds containing boraguanidinate ligands often leads to remarkable and unprecedented results. Herein, we report on the synthesis of the rare example of boraguanidinate-stabilized germylene 1 and its reactivity with selected inorganic and organic reagents. Observed results show that 1 may be a promising candidate for activation of various compounds for examples acetylenes, isonitriles or metal carbonyls.

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