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Study of reactivity of germylene stabilized by boraguanidinate ligand

Authors: Böserle Jiří | Dostál Libor

Year: 2015

Type of publication: ostatní - přednáška nebo poster

Page from-to: nestránkováno

Titles:

Language	Name	Abstract	Keywords
eng	Study of reactivity of germylene stabilized by boraguanidinate ligand	The investigation dealing with reactivity of germylene 1 containing in its structure a boraguanidinate ligand is presented. This type of dianionic N,N’-chelating ligands is derived from guanidinate ligands by a substitution a carbon atom by a boron atom and represents a relatively unexplored branch of organometallic chemistry.The electronic and steric properties of these ligands may be fine-tuned by the use of different substituents on the BN3 backbone. Another interesting property of these ligands is dianionic character which significantly affects their reactivity. Herein, we report on the synthesis of the rare example of boraguanidinate-stabilized germylene 1 and its reactivity with selected reagents. Observed results show that 1 may be a promising candidate for activation of various compounds especially small molecules.