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Bis(amido)phosphanes and their use as ligands for 14th group metals

Authors: Vrána Jan | Růžičková Zdeňka | Dostál Libor

Year: 2015

Type of publication: ostatní - přednáška nebo poster

Page from-to: nestránkováno

Titles:

Language	Name	Abstract	Keywords
eng	Bis(amido)phosphanes and their use as ligands for 14th group metals	Boramidinates and amidinates were used as suitable ligands for both transition and main group metals. Analogical compounds, bis(amido)phosphanes, were also proven to be as useful ligands in organometallic and coordination chemistry, but their chemistry was studied in significantly lower extent. Bis(amido)phosphanes may have a wide range of bonding properties, since they can act as both monoanionic and dianionic ligands, where the ligand is bonded by either covalent or coordination bond to the central atom. Novel germanium(II) and tin(II) bis(organoamido)phosphanes were prepared. Characterization of lithium and potassium precursors is also included.