Publication detail

Lewis-acid induced disaggregation of dimeric arylantimony oxides

Year: 2015

Type of publication: článek v odborném periodiku

Name of source: Chemical Communications

Publisher name: Royal Society of Chemistry

Place: Cambridge

Page from-to: 5932-5935

Titles:

Language	Name	Abstract	Keywords
cze	Lewis-acid indukovaný monomerizace arylantimonitých oxidů	Dimerní arylantimonité oxidy (Ph3SbO)(2) and [2,6-(Me2NCH2)(2)C6H3SbO](2) byly monomerizovány pomocí B(C6F5)(3).	Lewis-acid; indukovaná monomerizace; arylantimonité oxidy
eng	Lewis-acid induced disaggregation of dimeric arylantimony oxides	The previously known dimeric arylantimony oxides (Ph3SbO)(2) and [2,6-(Me2NCH2)(2)C6H3SbO](2) were disaggregated by the Lewis acid B(C6F5)(3) giving rise to the formation of the Lewis pair complexes Ph3SbOB(C6F5)(3) and 2,6-(Me2NCH2)(2)C6H3SbOB(C6F5)(3) having short bipolar single Sb-O bonds.	main-group compounds; triphenylphosphine oxide; triphenylstibine oxide; electron-density; dative bonds; crystal; disiloxane; reactivity; chemistry; efficient

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