Publication detail

N-Coordinated Tin(II) Trifluoromethanesulfonates and Their Reactions with Transition Metal Carbonyls

Year: 2015

Type of publication: článek v odborném periodiku

Name of source: Inorganic Chemistry

Publisher name: American Chemical Society

Place: Washington

Page from-to: 6792-6800

Titles:

Language	Name	Abstract	Keywords
cze	N-koordinované Cínaté Trifluorometansulfonáty a jejich reakce	Byly připravené N-koordinované Cínaté Trifluorometansulfonáty a byly studovány jejich reakce s přechodnými kovy. Tyto komplexy byly charakterizovány pomocí NMR spektroskopie a rentgenové difrakční analýzy.	trifluorometansulfonáty cínaté;přechodné kovy
eng	N-Coordinated Tin(II) Trifluoromethanesulfonates and Their Reactions with Transition Metal Carbonyls	The syntheses of the compounds [(LSnCl)-Sn-1][M-(CO)(5)(SnCl3)] (3, M = W; 4, M = Cr), [(LSnCl)-Sn-1]OTf (5), [(LSnCl)-Sn-1][W(CO)(5)(SnCl2OTf)] (6), [(LSnOTf)-Sn-1][OTf] (7), and [(LSn)-Sn-2(OTf)(2)] (8) with L-1 = {2,6-[(CH3)C=N(C6H3-2,6-Pr-i(2))(2)]C5H3N} (DIMPY) and L-2 = {2-[(CH3)C=N-(C6H3-2,6-Pr-i(2))]-6-(CH3O)}C5H3N) is reported. The compounds were characterized by elemental analyses, H-1, C-13, F-19, and Sn-119 NMR spectroscopy, electrospray ionization mass spectrometry, and single-crystal X-ray diffraction analyses (3 center dot 1.5C(7)H(8), 5 center dot CH2Cl2, 7 center dot C7H8, 8). For compounds 7 and 8, the experimental work is accompanied by density functional theory calculations.	main-group elements; molecular-orbital methods; bond covalent radii; gaussian-basis sets; tin cations; complexes; stabilization; germanium(ii); ligand; compound

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