Publication detail

Synthesis and structure of heavy group 15 metallastannoxanes [2,6-(Me2NCH2)(2)C6H3E](2,6-Mes(2)C(6)H(3)Sn)(3)O-3(OH)(5) (E = Sb, Bi)

Authors: Svoboda Tomáš | Warneke Jonas | Růžička Aleš | Dostál Libor | Beckmann Jens

Year: 2015

Type of publication: článek v odborném periodiku

Name of source: Journal of Organometallic Chemistry

Publisher name: ELSEVIER SCIENCE SA

Place: LAUSANNE

Page from-to: 171-173

Titles:

Language	Name	Abstract	Keywords
cze	Syntéza a struktura metallastannoxanů[2,6-(Me2NCH2)(2)C6H3E](2,6-Mes(2)C(6)H(3)Sn)(3)O-3(OH)(5) (E = Sb, Bi)	Byly charakterizovány nové struktura metallastannoxanů[2,6-(Me2NCH2)(2)C6H3E](2,6-Mes(2)C(6)H(3)Sn)(3)O-3(OH)(5) (E = Sb, Bi).	cín;antimon;bismut;metallastannoxany
eng	Synthesis and structure of heavy group 15 metallastannoxanes [2,6-(Me2NCH2)(2)C6H3E](2,6-Mes(2)C(6)H(3)Sn)(3)O-3(OH)(5) (E = Sb, Bi)	The reaction of the trans-cyclo-[2,6-Mes(2)C(6)H(3)Sn(O)(OH)](3) with the dimeric pnictogen(III) oxides [2,6-(Me2NCH2)(2)C6H3EO](2) (E = Sb, Bi) proceeds with mutual ring-opening and provided the novel tetranuclear metallastannoxanes [2,6-(Me2NCH2)(2)C6H3E](2,6-Mes(2)C(6)H(3)Sn)(3)O-3(OH)(5) (1, E = Sb; 2, E = Bi) that were fully characterized by X-ray crystallography.	Tin; Antimony; Bismuth; Metallstannoxanes; X-ray structures

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