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Coordination behavior of bis(1,2,4-diazaphosphol-1-yl)methane

Authors: Mlateček Martin | Dostál Libor | Erben Milan | Růžičková Zdeňka | Honzíček Jan

Year: 2016

Type of publication: ostatní - přednáška nebo poster

Page from-to: nestránkováno

Titles:

Language	Name	Abstract	Keywords
eng	Coordination behavior of bis(1,2,4-diazaphosphol-1-yl)methane	New anionic ligand, phenyl-tris(1,2,4-diazaphospholyl)borate (PhTdap), containing phosphorus heterocycle has been recently synthesised and characterized. [1] A series of transition and non-transition metal complexes have been prepared but only in one case the coordination via phosphorus atom was observed. Afterwards we synthesised neutral chelating ligand bis(1,2,4-diazaphospholyl)methane (Bdapm) and studied its properties. We find out, that Bdapm shows a variety of coordination modes that could yield multimetallic species. The structures and spectroscopic study of these new compounds will be discussed in presented contribution.	Coordination; transition metals; bis(1,2,4-diazaphosphol-1-yl)methane