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Addition of main group metal amides to various nitriles

Authors: Chlupatý Tomáš | Růžička Aleš

Year: 2016

Type of publication: ostatní - přednáška nebo poster

Page from-to: nestránkováno

Titles:

Language	Name	Abstract	Keywords
eng	Addition of main group metal amides to various nitriles	The activation of small molecules together with reactions of main group metal complexes and organometallics with unsaturated systems is one of the hottest topic of nowadays chemistry. In this paper, we would like to demonstrate the reactivity of various lithium, magnesium, aluminium and tin complexes with unsaturated systems such as alkynes and various aliphatic and aromatic nitriles and dinitriles. These reactions are usually connected to the presence of lowest possible oxidation state of the central metal atom as well as the possibility of the trimethylsilyl group, present in the amide backbone, migration process to the nitrogen atom(s) of parent nitrile group. Various organic molecules or natural products can be synthesized by our approach.