Publication detail

Stibinidene and Bismuthinidene as Two-Electron Donors for Transition Metals (Co and Mn)

Year: 2016

Type of publication: článek v odborném periodiku

Name of source: Chemistry - A European Journal

Publisher name: Wiley-VCH

Place: Weinheim

Page from-to: 7376-7380

Titles:

Language	Name	Abstract	Keywords
cze	Sloučeniny jednomocného antimonu a bismutu jako ligandy pro přechodné kovy	Reakce ArM [Ar=C6H3-2,6-(CH=NtBu)(2); M=Sb (1), Bi (2)] s Co-2(CO)(8) a Mn-2(CO)(10) vedly k [(ArM)(2)Co(CO)(3)](+)[Co(CO)(4)](-) a [(ArM)(2)Mn(CO)(4)](+)[Mn(CO)(5)](-) [ M=Sb (3, 5), Bi (4, 6)].	antimon; bismut; ligandy; přechodné kovy
eng	Stibinidene and Bismuthinidene as Two-Electron Donors for Transition Metals (Co and Mn)	The reaction of stibinidene and bismuthinidene ArM [where Ar=C6H3-2,6-(CH=NtBu)(2); M=Sb (1), Bi (2)] with transition metal (TM) carbonyls Co-2(CO)(8) and Mn-2(CO)(10) produced unprecedented ionic complexes [(ArM)(2)Co(CO)(3)](+)[Co(CO)(4)](-) and [(ArM)(2)Mn(CO)(4)](+)[Mn(CO)(5)](-) [where M=Sb (3, 5), Bi (4, 6)]. The pnictinidenes 1 and 2 behaved as two-electron donors in this set of compounds. Besides the M -> TM bonds, the topological analysis also revealed a number of secondary interactions contributing to the stabilization of cationic parts of titled complexes.	bond theory; donor-acceptor systems; Lewis bases; ligand design; main group elements

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