Publication detail

Intramolecularly coordinated galium sulfides: Suitable single source precursors for GaS thin films

Year: 2016

Type of publication: článek v odborném periodiku

Name of source: Chemistry - A European Journal

Page from-to: 18817 -18823

Titles:

Language	Name	Abstract	Keywords
cze	Intramolekulárně koordinované organogalité sulfidy: Prekurzory pro GaS tenké vrstvy	Byly připravené intramolekulárně koordinované organogalité sulfidy. Tyto sloučeniny byly využity jako prekurzory pro přípravu GaS tenké vrstvy.	Intramolekulárně koordinované organogalité sulfidy; tenké vrstvy
eng	Intramolecularly coordinated galium sulfides: Suitable single source precursors for GaS thin films	The studies have been focused on the synthesis of N -> Ga coordinated organogallium sulfides [(LGa)-Ga-1(mu-S)](3) (1) and [(LGa)-Ga-2(mu-S)](2) (2) containing either N,C,N- or C,N-chelating ligands L-1 or L-2 (L-1 is {2,6-(Me2NCH2)(2)C6H3}(-) and L-2 is {2-(Et2NCH2)-4,6-tBu(2)-C6H2}(-)). As the result of the different ligands, compounds 1 and 2 differ mutually in their structure. To change the Ga/S ratio, unusually N -> Ga coordinated or-ganogallium tetrasulfide (LGa)-Ga-1(kappa(2)-S-4) (3) was prepared and the unprecedented complex [{2-[CH{(CH2)(3)CH3}(mu-OH)]-6-CH2NMe2} C6H3] GaS (4) was also isolated as the minor by product of the reaction. Compounds 1-3 were further studied as potential single-source precursors for amorphous GaS thin film deposition by spin-coating.	NMR spectroscopy; spin coating; thin-layer films

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