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Analysis of Ni species formed on zeolites, mesoporous silica and alumina supports and their catalytic behavior in the dry reforming of methane
Authors: Drobná Helena | Kout Martin | Soltysek Agnieszka | Gonzalez-Delacruz Victor M. | Caballero Alfonso | Čapek Libor
Year: 2017
Type of publication: článek v odborném periodiku
Name of source: Reaction Kinetics Mechanisms and Catalysis
Publisher name: Springer
Place: Heidelberg
Page from-to: 255-274
Titles:
Language Name Abstract Keywords
cze Analýza částic Ni nanesených na zeolitech, mezoporézní silice a alumině a jejich katalytické chování při suchém reformování methanu Bylo studováno katalytické chování částic niklu nanesených na vybraných typech zeolitů (MFI a FAU), mezoporézních materiálů (Al-MCM-41 a SBA-15) a aluminy při reakci suchého reformování methanu ve vztahu k jejich strukturním vlastnostem. suché reformování; methan; nikl; katalýza; velikost částic
eng Analysis of Ni species formed on zeolites, mesoporous silica and alumina supports and their catalytic behavior in the dry reforming of methane The presented investigation is focused on the analysis of Ni species formed on microporous (zeolites MFI and FAU) and mesoporous materials (Al-MCM- 41 and SBA-15) and alumina supports and their catalytic behavior in the dry reforming of methane. The paper lays emphasis on the relationship between the catalytic behavior of Ni-based catalysts and their textural/structural properties. Ni-based catalysts were prepared by wet impregnation (11 wt% of Ni) followed by calcination in air and reduction in hydrogen. The properties of Ni-based catalysts were also compared prior and after the catalytic tests. The critical role was played by the high value of the specific surface area and the high strength of the interaction between the Ni species and the support, which both determined the high dispersion and stability of metal Ni-0 particles. Ni-Al-MCM-41 and Ni-SBA-15 showed the values of the conversion of CO2 and CH4 above 90% (stable during 12 h). Slightly lower values of the conversion of CO2 and CH4 were observed over Ni-Al2O3 (also stable during 12 h). In contrast to these materials, Ni-MFI and Ni-FAU exhibited the worse metallic Ni-0 particles dispersion and very bad catalytic behavior. Dry reforming; Methane; Nickel; Catalysis; Particle size

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