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Publication detail

High Temperature Formation and Thermal Resistance of Li1+xCrxZr2-x(PO4)3 Solid Solutions
Year: 2017
Type of publication: ostatní - článek ve sborníku
Name of source: Book of Abstracts of JTACC + V4
Publisher name: Akadémiai Kiadó
Place: Budapešť
Page from-to: 203-204
Titles:
Language Name Abstract Keywords
eng High Temperature Formation and Thermal Resistance of Li1+xCrxZr2-x(PO4)3 Solid Solutions In this contribution, the mechanism of the formation, structure and thermal resistance of a series of framework phosphates – solid solutions of Li1+xCrxZr2-x(PO4)3 – is discussed. The samples were prepared by high temperature solid state reaction. Thermal transformation in the reaction mixtures of (0.5+x/2)Li2CO3-(2-x)ZrOCl2∙8H2O-(x/2)Cr2O3-3(NH4)2HPO4 was investigated using TG-DTA analysis (20-1200 °C). Evolution of the phase composition during heating was analysed using powder XRD analysis. Combination of both techniques helped to understand the mechanism of the formation of the solid solutions and the chemical processes taking place in the mixtures during heating. Ceramic;thermal stability;solid state reaction;NASICON