University of PardubiceFaculty of Chemical Technology

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New approach for stabilization of low-hapticity indenyl complexes

Authors: Mrózek Ondřej | Vinklárek Jaromír | Honzíček Jan

Year: 2017

Type of publication: ostatní - přednáška nebo poster

Page from-to: nestránkováno

Titles:

Language	Name	Abstract	Keywords
eng	New approach for stabilization of low-hapticity indenyl complexes	Over the last decade, indenyl (C9H7) complexes of transition metal attracting increased attention due to pronounced acceleration of organometallic reaction and higher catalytic activity compared to cyclopentadienyl analogs. Although this phenomenon was rationalized through lower activation energy of haptotropic rearrangement of the C9H7, the prediction and design of indenyl complexes with specific chemical behavior still remain challenging. Key step for the fundamental understanding of the unusual reactivity of indenyl complexes is characterization of low-hapticity species, which may be formed during the organometallic reactions of catalytic cycles. The following post is focused on the synthesis of highly stable h3-indenyl complexes with intramolecularly coordinated nitrogen donor.	indenyl; molybdenum