Publication detail

N,C,N-chelated antimony(III), bismuth(III) and tin(IV) derivatives of 1,1'-ferrocenedicarboxylic acid

Authors: Jambor Roman | Růžičková Zdeňka | Erben Milan | Dostál Libor

Year: 2017

Type of publication: článek v odborném periodiku

Name of source: Inorganic Chemistry Communications

Page from-to: 36-39

Titles:

Language	Name	Abstract	Keywords
cze	N,C,N-chelatované antimonité, bismutité a cíničité deriváty 1,1'-ferrocenedikarboxylové kyseliny	Byly připraveny a studovány N,C,N-chelatované antimonité, bismutité a cíničité deriváty 1,1'-ferrocenedikarboxylové kyseliny
eng	N,C,N-chelated antimony(III), bismuth(III) and tin(IV) derivatives of 1,1'-ferrocenedicarboxylic acid	N,C,N-intramolecularly coordinated antimony(111) and bismuth(Ill) oxides (ArMO)(2) [where Ar = [2,6(Me2NCH2)(2)C6H3]-, M = Sb (1) or Bi (2)] reacted with 1,1'-ferrocenedicarboxylic acid fc(COOH)2 (fc = ferrocene-1,1'-diyl) under formation of corresponding carboxylates fc(COO)(2)SbAr (4) and Ifc(COO)(2)BiArb (5). Similarly, the treatment of fc(COOH)(2) with tin(IV) carbonate ArSnPhCO3 (3) led to the carboxylate fc(COO)(2)Sn(Ph)Ar (6). All compounds were characterized by the help of multinuclear NMR, Raman, IR and UV-Vis spectroscopy and in the case of 4 and 5 using single -crystal X-ray diffraction analysis.	Antimony; Bismuth; Tin; Chelating ligands; Carboxylates; Ferrocene

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