Login for students

Login for employees

Publication detail

Application of Oxovanadium Complex Stabilized by N,N,N,N-Chelating Ligand in Air-Drying Paints
Authors: Charamzová Iva | Vinklárek Jaromír | Kalenda Petr | Honzíček Jan
Year: 2018
Type of publication: článek v odborném periodiku
Name of source: Coatings
Publisher name: MDPI AG (Multidisciplinary Digital Publishing Institute)
Place: Basel
Page from-to: "204-1"-"204-9"
Titles:
Language Name Abstract Keywords
cze Využití oxovanadičitého komplexu s N,N,N,N-chelatujícím ligandem v nátěrových hmotách Byla stanovena sikativační aktivita nového sikativu na bázi vanadu, který obsahuje makrocyklický chelatující ligand. Mechanické zkoušky na zkušebních nátěrech alkydů různé olejové délky byly doplněny spektroskopickými měněními. Infračervená spektroskopie s časovým rozlišením byla použita k určení kinetických parametrů autooxidace a elektronová paramagnetická rezonance k určení stability vanadičitého komplexu v zaschlých filmech. vanad; nátěrová hmota; alkydová pryskyřice; autooxidace
eng Application of Oxovanadium Complex Stabilized by N,N,N,N-Chelating Ligand in Air-Drying Paints New vanadium-based drier, stabilized with macrocyclic chelating ligand, is described. Its drying activity was established on solvent-borne alkyd resins of different oil-length modified by soybean oil. The test coatings were characterized by standardized mechanical tests as well as spectroscopic methods. Time-resolved infrared spectroscopy was used for determination of kinetic parameters of the autoxidation process while the EPR (electron paramagnetic resonance) spectroscopy enabled confirmation of stability of oxovanadium(IV) species in the cured films. The obtained experimental data revealed promising catalytic activity of the oxovanadium(IV) compound stabilized with N,N,N,N-chelating ligand at low concentration. At 0.03 wt % of metal in dry matter content, it shows short total dry times not exceeding 12 h while commercial cobalt(II) 2-ethylhexanoate is, at the same concentration, considerably lower active with total dry times 15.4 h (alkyd of short oil-length) and >24 h (alkyd of medium oil-length). oxovanadium; air-drying paint; alkyd resin; autoxidation

Departments

Other Parts

Map

en.mapy.cz

Services

Popular Links

© 2023 University of Pardubice, Studentská 95, 532 10 Pardubice 2
Phone: +420 466 036 111, 466 036 112, 466 036 113
Webmaster, RSS
Data box ID: f5vj9hu
Accessibility Statement
CC BY-NC-ND 4.0Creative CommonsAttributionNonCommercialNoDerivatives