Publication detail

Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides

Year: 2018

Type of publication: článek v odborném periodiku

Name of source: Dalton Transactions

Publisher name: Royal Society of Chemistry

Place: Cambridge

Page from-to: 14880-14883

Titles:

Language	Name	Abstract	Keywords
cze	Reaktivita boraguanidinatových germylenů s organickými substráty	Byla studována reaktivita boraguanidinatových germylenů (i-Pr)(2)NB(NDmp)(2)Ge (Dmp = 2,6-Me2C6H3) s organickými substráty RN3 a RNCS.	Reaktivita; boraguanidinatových; germylenů; organickými; substráty
eng	Diverse reactivity of a boraguanidinato germylene toward organic pseudohalides	The reactions of the boraquanidinato germylene (i-Pr)(2)NB(NDmp)(2)Ge (1) (Dmp = 2,6-Me2C6H3) with RN3 and RNCS produced rare examples of Ge2N and Ge3S rings, while the treatment of 1 with RNCO led to an insertion into the N-Ge bond leading to a novel type of germylene stabilized within a six membered ring, i.e. [N(R)C(O)N(Dmp)B(N(i-Pr)(2))N(Dmp)]Ge (R = t-Bu or Ad).	n-heterocyclic germylene; bond covalent radii; coordination chemistry; physical-properties; metal alkyls; activation; complexes; elements; amides; azadigermiridines

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