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Fundamental Aspects of Property Tuning in Push-Pull Molecules: Towards Pyrazine Photoredox Catalyst with Tailored Properties

Authors: Bureš Filip | Hloušková Zuzana

Year: 2019

Type of publication: ostatní - přednáška nebo poster

Page from-to: nestránkováno

Titles:

Language	Name	Abstract	Keywords
eng	Fundamental Aspects of Property Tuning in Push-Pull Molecules: Towards Pyrazine Photoredox Catalyst with Tailored Properties	The contribution will focus on main principles of property tuning in push-pull molecules, especially in terms of structure-property relationships. Successful application of push-pull molecules in photoredox catalysis will be emphasized. 5,6-Disubstituted pyrazine-2,3-dicarbonitrile bearing 5 methoxythiophen-2-yl substituents has been developed and will be presented as efficient visible light induced photoredox catalysts. Its catalytic performance will be demonstrated in cross-dehydrogenative coupling (CDC), chemodivergent CDC reaction utilizing itaconimide, indole oxidations towards isatin or formylformanilides and also enantioselective C-H olefinations.	Push-Pull Molecules; Photoredox Catalyst; Pyrazine; Cross-dehydrogenative Coupling; Chemodivergent