Publication detail

Iron(II) complex with modified bispidine ligand: Synthesis and catalytic alkyd drying

Authors: Křižan Martin | Vinklárek Jaromír | Erben Milan | Růžičková Zdeňka | Honzíček Jan

Year: 2019

Type of publication: článek v odborném periodiku

Name of source: Inorganica Chimica Acta

Publisher name: Elsevier Science SA

Place: Lausanne

Page from-to: 636-641

Titles:

Language	Name	Abstract	Keywords
cze	Železnatý komplex s modifikovaným bispidinovým ligandem: Příprava a katalytické zasychání alkydů.	Železnatý komplex s modifikovaným bispidinovým ligandem byl připraven a charakterizován analytickými metodami, které zahrnovaly RTG analýzu na monokrystalu. Katalytická aktivita tohoto komplexu byla studována na alkydu dlouhé olejové délky.	železo; bispidin; RTG struktura; alkyd; autooxidace
eng	Iron(II) complex with modified bispidine ligand: Synthesis and catalytic alkyd drying	Modified iron(II) bispidine complex was synthesized and characterized by analytical methods including crystal structure determination on single crystal. Catalytic activity of the title compound toward autoxidation process was established on alkyd resin of long oil length. The standardized mechanical tests as well as kinetic studies, performed on thin layers of alkyd coatings, revealed high activity at considerably lower concentrations than usual for commercial cobalt(II) 2-ethylhexanoate. Due to high solubility in non-polar solvents, title compound is applicable without necessity of pre-dissolution in a polar organic solvent as in case of parent [Fe(bispi)Cl]Cl.	Iron; Bispidine; X-ray structure; Alkyd paints; Autoxidation

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