Publication detail

Modified Ferrocenes as Primary Driers for Formulations of Alkyd Paints

Authors: Honzíček Jan | Fedorova Tatiana | Vinklárek Jaromír | Mikysek Tomáš | Císařova Ivana

Year: 2020

Type of publication: článek v odborném periodiku

Name of source: Coatings

Publisher name: MDPI

Place: BASEL

Page from-to: "873-1"-"873-14"

Titles:

Language	Name	Abstract	Keywords
cze	Modifikované ferroceny jako sikativy pro formulace alkydových nátěrových hmot	Vliv modifikace benzoylferrocenů na jejich sikativační aktvitu byl studován na alkydové pryskyřici střední olejové délky.	ferrocen; alkyd; náhrada kobaltu; RTG difrakční analýza; autooxidace; elektrochemie
eng	Modified Ferrocenes as Primary Driers for Formulations of Alkyd Paints	The effect of modification of benzoylferrocene periphery on catalytic activity toward drying of alkyd resins has been investigated by the combination of experimental techniques. A series of substituted ferrocenes have been synthesized and characterized by analytical and spectroscopic tools including X-ray diffraction analysis on single crystals. The electrochemical behavior of the ferrocene derivatives has been elucidated by cyclic voltammetry and rotation disk voltammetry. The activity toward room temperature curing of alkyd resin has been evaluated by standard mechanical tests on coated plates, which enabled to establish a structure/catalytic activity relationship. Fast drying of test coatings has been observed for formulations of (3-methoxybenzoyl) ferrocene. Time-resolved infrared spectroscopy in combination with attenuated total reflectance sampling technique enabled to reveal the kinetic origin of the improved performance for this ferrocene derivative.	ferrocene; air-drying paint; alkyd; drier; cobalt replacement; X-ray diffraction; autoxidation; electrochemistry

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