Publication detail

Raman spectroscopy study of glass corrosion

Authors: Hruska Branislav | Gavenda Tadeas | Vasicek Filip | Svoboda Roman

Year: 2020

Type of publication: článek v odborném periodiku

Name of source: Vibrational Spectroscopy

Publisher name: Elsevier Science BV

Place: Amsterdam

Page from-to: "103096-1"-"103096-8"

Titles:

Language	Name	Abstract	Keywords
cze	Ramanova spektroskopická studie koroze skel	Binární skla Na2O-SiO2 a K2O-SiO2 s různými obsahem alkálií byla vystavena korozivnímu prostředí koncentrované HCl a následně podrobena Ramanově spektroskopické analýze.	silikátová skla; Ramanova spektroskopie; koroze; skelný povrch; skelná struktura
eng	Raman spectroscopy study of glass corrosion	Binary sodium silicate and potassium silicate glasses with different alkali content were exposed to the corrosion environment of 35 % hydrochloric acid (HCl). Glass samples were measured by Raman spectroscopy and the spectra were compared with Raman spectra of original pristine glasses in order to observe structural changes induced by corrosion within the surface layer. The usage of confocal Raman spectroscope enabled the measurement of Raman spectra from the depths of few micrometres to document the range of structural changes. The results suggest the depolymerisation of silicate structure due to the growth of the corrosion layer on the surface. The decrease of D2 peak points at the decomposition of three-membered rings. In addition, it is assumed that the Si-O-Si angle changes within the surface layer.	Alkali silicate glass; Raman spectroscopy; Corrosion; Glass surface; Glass structure

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