Publication detail

N -> Ge Coordinated Germylenes as Ligands for Monomeric Cu Complexes

Authors: Vítek Dominik | Dostál Libor | Růžička Aleš | Mikysek Tomáš | Jambor Roman

Year: 2021

Type of publication: článek v odborném periodiku

Name of source: European Journal of Inorganic Chemistry

Publisher name: Wiley-VCH

Place: Weinheim

Page from-to: 3301-3304

Titles:

Language	Name	Abstract	Keywords
cze	N -> Ge koordinované germyleny jako ligandy pro Cu komplexy	Byla studována možnost využití L(Cl)Ge (L=2-Et2NCH2-4,6-tBu(2)-C6H2) jako ligandu pro Cu komplexy. Byly připraveny [L(Cl)Ge](2)CuX (X=2: X=OAc, 3: X=OTf) komplexy.	Koordinační chemie; komplex Cu; germanium; hydrid; NMR spektroskopie
eng	N -> Ge Coordinated Germylenes as Ligands for Monomeric Cu Complexes	Synthesis of monomeric Cu complexes stabilized by the N -> Ge coordinated germylene L(Cl)Ge (L=2-Et2NCH2-4,6-tBu(2)-C6H2) is reported. The reactions of the [L(Cl)Ge](2)CuI (1) with AgX provided the complexes [L(Cl)Ge](2)CuX (X=2: X=OAc, 3: X=OTf) by selective substitution of the CuI bond. In contrast, the reaction of 1 with K[BEt3H] provided [L(H)Ge](2)CuI (4), the product of selective substitution of the GeCl bonds. The 4 represents the first example of Cu complex stabilized by two organogermaniun hydrides [L(H)Ge].	Coordination chemistry; Cu complex; Germanium; Hydride; NMR spectroscopy

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