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Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol
Authors: Aman Michal | Dostál Libor | Růžička Aleš | Tydlitát Jiří | Beckmann Jens | Turek Jan | Jambor Roman
Year: 2021
Type of publication: článek v odborném periodiku
Name of source: Chemical Communications
Publisher name: Royal Society of Chemistry
Place: Cambridge
Page from-to: 12992-12995
Titles:
Language Name Abstract Keywords
cze Sn,P-koordinovaný Ru kation: Katalyzátor pro aerobní oxidace benzylaminu a benzyl alkoholu Byl připraven stabilní Sn,P-koordinovaný Ru kation. Tento komplex je výborný katalyzátor pro aerobní oxidace benzylaminu a benzyl alkoholu. selektivní tvorba iminů; aminy; dehydrogenace; komplexy
eng Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol A stable ionic kappa Sn-2,P-coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine peri-substituted naphthalene ligand, which can act as either a reducing agent for a Ru(iii) complex or as a kappa Sn-2,P-chelating ligand for Ru(ii) compounds. selective imine formation; amines; dehydrogenation; acceptorless; mechanism; efficient; complexes; silylene; si