Publication detail

Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol

Year: 2021

Type of publication: článek v odborném periodiku

Name of source: Chemical Communications

Publisher name: Royal Society of Chemistry

Place: Cambridge

Page from-to: 12992-12995

Titles:

Language	Name	Abstract	Keywords
cze	Sn,P-koordinovaný Ru kation: Katalyzátor pro aerobní oxidace benzylaminu a benzyl alkoholu	Byl připraven stabilní Sn,P-koordinovaný Ru kation. Tento komplex je výborný katalyzátor pro aerobní oxidace benzylaminu a benzyl alkoholu.	selektivní tvorba iminů; aminy; dehydrogenace; komplexy
eng	Sn,P-coordinated Ru cation: a robust catalyst for aerobic oxidations of benzylamine and benzyl alcohol	A stable ionic kappa Sn-2,P-coordinated Ru complex shows excellent catalytic activity in aerobic oxidations of benzylamine and benzyl alcohol. This complex is stabilized by a stannylene-phosphine peri-substituted naphthalene ligand, which can act as either a reducing agent for a Ru(iii) complex or as a kappa Sn-2,P-chelating ligand for Ru(ii) compounds.	selective imine formation; amines; dehydrogenation; acceptorless; mechanism; efficient; complexes; silylene; si

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