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Benz[e]indenyl and benz[f]indenyl molybdenum compounds: evidence of the η3-coordination mode
Authors: Štěpán Jiří | Vinklárek Jaromír | Císařová Ivana | Dostál Libor | Honzíček Jan
Year: 2023
Type of publication: článek v odborném periodiku
Name of source: New Journal of Chemistry
Page from-to: 21396-21403
Titles:
Language Name Abstract Keywords
cze Benz[e]indenyl a benz[f]indenylmolybdenové sloučeniny: důkaz η3-koordinačního módu Tato studie popisuje syntézu a charakterizaci nových sloučenin molybdenu nesoucích benz[e]indenyl a benz[f]indenyl ligandy. Schopnost ligandů podstoupit η5-η3 haptotropní přesmyk byla prokázána při reakcích s tris(pyrazolyl)methanem. Vzhled η3-koordinačního módu byl stanoven NMR spektroskopií a rentgenovou strukturní analýzou na monokrystalu. molybden; indenyl
eng Benz[e]indenyl and benz[f]indenyl molybdenum compounds: evidence of the η3-coordination mode This study reports the synthesis and characterization of new molybdenum compounds bearing benz[e]indenyl and benz[f]indenyl ligands. The capability of the ligands to undergo η5-to-η3 haptotropic rearrangement was evidenced on reactions with tris(pyrazolyl)methane. Appearance of the η3-coordination mode was determined by NMR spectroscopy and X-ray structure analysis on a single crystal. molybdenum; indenyl