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The Crystallization Behavior of a Na2O-GeO2-P2O5 Glass System: A (Micro)Structural, Electrical, and Dielectric Study
Authors: Marijan Sara | Razum Marta | Kerhac Kristina Sklepic | Mošner Petr | Koudelka Ladislav | Pisk Jana | Mogus-Milankovic Andrea | Skoko Zeljko | Pavic Luka
Year: 2024
Type of publication: článek v odborném periodiku
Name of source: Materials
Publisher name: MDPI
Place: BASEL
Page from-to: 306
Titles:
Language Name Abstract Keywords
cze Studium krystalizace skel systému Na2O-GeO2-P2O5: Struktura, elektriické a dielektrické vlastnosti Byl studován vliv 24 hodinové temperace skel systému Na2O-GeO2-P2O5 na jejich (mikro)strukturu, elektrické a dielektrické vlastnosti s použitím různých technik jako je prášková rentgenová difrakce, infračervená spektroskopie, skenovací elektronová mikroskopie aj. fosforečnanová skla; sklokeramika; krystalizace, struktura; vlastnosti
eng The Crystallization Behavior of a Na2O-GeO2-P2O5 Glass System: A (Micro)Structural, Electrical, and Dielectric Study Sodium-phosphate-based glass-ceramics (GCs) are promising materials for a wide range of applications, including solid-state sodium-ion batteries, microelectronic packaging substrates, and humidity sensors. This study investigated the impact of 24 h heat-treatments (HT) at varying temperatures on Na-Ge-P glass, with a focus on (micro)structural, electrical, and dielectric properties of prepared GCs. Various techniques such as powder X-ray diffraction (PXRD), infrared spectroscopy-attenuated total reflection (IR-ATR), and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) were employed. With the elevation of HT temperature, crystallinity progressively rose; at 450 degrees C, the microstructure retained amorphous traits featuring nanometric grains, whereas at 550 degrees C, HT resulted in fully crystallized structures characterized by square-shaped micron-scale grains of NaPO3. The insight into the evaluation of electrical and dielectric properties was provided by Solid-State Impedance Spectroscopy (SS-IS), revealing a strong correlation with the conditions of controlled crystallization and observed (micro)structure. Compared to the initial glass, which showed DC conductivity (sigma(DC)) on the order of magnitude 10(-7) Omega(-1) cm(-1) at 393 K, the obtained GCs exhibited a lower sigma(DC) ranging from 10(-8) to 10(-10) Omega(-1) cm(-1). With the rise in HT temperature, sigma(DC) further decreased due to the crystallization of the NaPO3 phase, depleting the glass matrix of mobile Na+ ions. The prepared GCs showed improved dielectric parameters in comparison to the initial glass, with a noticeable increase in dielectric constant values (similar to 20) followed by a decline in dielectric loss (similar to 10(-3)) values as the HT temperatures rise. Particularly, the GC obtained at @450 stood out as the optimal sample, showcasing an elevated dielectric constant and low dielectric loss value, along with moderate ionic conductivity. This research uncovers phosphate glasses; phosphate glass-ceramics; controlled crystallization; (micro)structure-property relationship; IR-ATR; PXRD; SEM-EDS; Solid-State Impedance Spectroscopy (SS-IS)

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