Ing. Karel Frolich, Ph.D.

Education and academic qualifications

Job overview

Study and work stay

Publications

HÁJEK, M. - HÁJEK, T. - KOCIÁN, D. - FROLICH, K. - PELLER, A. Epoxidation of Methyl Esters as Valuable Biomolecules: Monitoring of Reaction Molecules, 2023, vol. 28, no. 6, s. "2819-1"-"2819-15". ISSN: 1420-3049.

MÜCK, J. - KOCIK, J. - FROLICH, K. - SIMEK, J. - MICHALKOVA, M. - HÁJEK, M. Transition Metal-Promoted Mg-Fe Mixed Oxides for Conversion of Ethanol to Valuable Products ACS Omega, 2023, vol. 8, no. 22, s. 19374-19384. ISSN: 2470-1343.

FROLICH, K. - KOCÍK, J. - MÜCK, J. - KOLENA, J. - SKUHROVCOVÁ, L. The role of Zn in the Cu-Zn-Al mixed oxide catalyst and its effect on glycerol hydrogenolysis Molecular Catalysis, 2022, vol. 533, no. December, s. "112796-1"-"112796-8". ISSN: 2468-8231.

KOCIÁN, D. - HÁJEK, M. - VÁVRA, A. - FROLICH, K. - KOCIK, J. The influence of residue sodium ions in mixed oxide on catalytic activity in transesterification of vegetable oil Molecular Catalysis, 2022, vol. 517, no. January, s. "112017-1"-"112017-10". ISSN: 2468-8231.

MÜCK, J. - KOCÍK, J. - HÁJEK, M. - TIŠLER, Z. - FROLICH, K. - KAŠPÁREK, A. Transition metals promoting Mg-Al mixed oxides for conversion of ethanol to butanol and other valuable products: Reaction pathways Applied catalysis A: General, 2021, vol. 626, no. September, s. "118380-1"-"118380-8". ISSN: 0926-860X.

MALISOVA, M. - HORNAVEK, M. - MIKULEC, J. - HUDEC, P. - HÁJEK, M. - PELLER, A. - JORIK, V. - FROLICH, K. - HADVINOVA, M. - HAJEKOVA, E. Transesterification of Camelina sativa Oil Catalyzed by Mg/Al Mixed Oxides with Added Divalent Metals ACS Omega, 2020, vol. 5, no. 49, s. 32040-32050. ISSN: 2470-1343.

FROLICH, K. - VÁVRA, A. - KOCÍK, J. - HÁJEK, M. - JÍLKOVÁ, A. The long-term catalytic performance of mixed oxides in fixed-bed reactors in transesterification Renewable Energy, 2019, vol. 143, no. December, s. 1259-1267. ISSN: 0960-1481.

KOCÍK, J. - FROLICH, K. - PERKOVÁ, I. - HORACEK, J. Pyroaurite-based Mg-Fe mixed oxides and their activity in aldol condensation of furfural with acetone: effect of oxide composition Journal of Chemical Technology and Biotechnology, 2019, vol. 94, no. 2, s. 435-445. ISSN: 0268-2575.

GANJKHANLOU, Y. - TIŠLER, Z. - HIDALGO, J. - FROLICH, K. - KOTERA, J. - ČIČMANEC, P. - BULÁNEK, R. VOx/Zr-SBA-15 catalysts for selective oxidation of ethanol to acetaldehyde Chemical Papers, 2018, vol. 72, no. 4, s. 937-946. ISSN: 0366-6352.

GANJKHANLOU, Y. - BULÁNEK, R. - KIKHTYANIN, O. - FROLICH, K. Study on thermal stabilities and symmetries of chemisorbed species formed on K-zeolites upon CO2 adsorption by TPD and in situ IR spectroscopy Journal of Thermal Analysis and Calorimetry, 2018, vol. 133, no. 1, s. 355-364. ISSN: 1388-6150.

HÁJEK, M. - VÁVRA, A. - JÍLKOVÁ, A. - FROLICH, K. - KOCÍK, J. The influence of various precursors on properties of Mg-Fe hydrotalcites and mixed oxides. In 50. Symposium on Catalysis : book of abstracts. Praha: Ústav fyzikální chemie Jaroslava Heyrovského AV ČR, 2018. s. Po11 s. ISBN 978-80-87351-53-6.

VÁVRA, A. - HÁJEK, M. - JÍLKOVÁ, A. - FROLICH, K. - KOCÍK, J. Using of Mg-Al and Mg-Fe mixed oxides in transesterification in fixed-bed reactor. In 50. Symposium on Catalysis : book of abstracts. Praha: Ústav fyzikální chemie Jaroslava Heyrovského AV ČR, 2018. s. Po49 s. ISBN 978-80-87351-53-6.

VÁVRA, A. - HÁJEK, M. - FROLICH, K. - KOCÍK, J. - JÍLKOVÁ, A. The cataytic performance of Mg/Al and Mg/Fe mixed oxides in transesterification in flow reactor. In 13th conference on sustainable development of energy, water and environment systems : book of abstracts. Zagreb: University of Zagreb, 2018. s. 286-286 s.

SMOLÁKOVÁ, L. - FROLICH, K. - KOCÍK, J. - KIKHTYANIN, O. - ČAPEK, L. Surface Properties of Hydrotalcite-Based Zn(Mg)Al Oxides and Their Catalytic Activity in Aldol Condensation of Furfural with Acetone Industrial & Engineering Chemistry Reseach, 2017, vol. 56, no. 16, s. 4638-4648. ISSN: 0888-5885.

HÁJEK, M. - KOCÍK, J. - FROLICH, K. - VÁVRA, A. Mg-Fe mixed oxides and their rehydrated mixed oxides as catalysts for transesterification Journal of Cleaner Production, 2017, vol. 161, no. September, s. 1423-1431. ISSN: 0959-6526.

SMOLÁKOVÁ, L. - FROLICH, K. - TROPPOVÁ, I. - KUTÁLEK, P. - KROFT, E. - ČAPEK, L. Determination of basic sites in Mg-Al mixed oxides by combination of TPD-CO2 and CO2 adsorption calorimetry Journal of Thermal Analysis and Calorimetry, 2017, vol. 127, no. 3, s. 1921-1929. ISSN: 1388-6150.

FROLICH, K. - KOCÍK, J. - HÁJEK, M. - VÁVRA, A. Hydrotalcite based Mg/Fe oxides with varying acido-basic properties. In 7th Czech-Italian-Spanish Symposium on Catalysis : program and abstracts. Praha: Ústav fyzikální chemie Jaroslava Heyrovského AV ČR, 2017. s. PO13 s. ISBN 978-80-87351-42-0.

KOTERA, J. - BULÁNEK, R. - ČIČMANEC, P. - GANJKHANLOU, Y. - FROLICH, K. VOx/Zr-SBA-15 katalyzátory pro selektivní oxidaci ethanolu na acetaldehyd. In Studentská vědecká odborná činnost 2016/2017 : sborník příspěvků. Pardubice: Univerzita Pardubice, 2017. s. 89-94 s. ISBN 978-80-7560-084-4.

HÁJEK, M. - KOCÍK, J. - FROLICH, K. - VÁVRA, A. Mg-Fe mixed oxides and their rehydrated mixed oxides as catalysts for transesterification. In 49th Symposium on Catalysis : book of abstracts. Praha: Ústav fyzikální chemie Jaroslava Heyrovského AV ČR, 2017. s. PO09 s. ISBN 978-80-87351-47-5.

PERKOVÁ, I. - FROLICH, K. - HÁJEK, M. - VÁVRA, A. - KOCÍK, J. Mixed Mg/Fe oxides from hydrotalcites as catalysts for aldol condensation: Effect of Mg/Fe ratio. In 49th Symposium on Catalysis : book of abstracts. Praha: Ústav fyzikální chemie Jaroslava Heyrovského AV ČR, 2017. s. PO27 s. ISBN 978-80-87351-47-5.

KIKHTYANIN, O. - BULÁNEK, R. - FROLICH, K. - ČEJKA, J. - KUBIČKA, D. Aldol condensation of furfural with acetone over ion-exchanged and impregnated potassium BEA zeolites Journal of Molecular Catalysis A: Chemical, 2016, vol. 424, no. December, s. 358-368. ISSN: 1381-1169.

TCHANG, H. - FROLICH, K. - SHAMZHY, M. - ELIASOVA, P. - RUBES, M. - CEJKA, J. - BULÁNEK, R. - NACHTIGALL, P. The effect of the zeolite pore size on the Lewis acid strength of extra-framework cations Physical Chemistry Chemical Physics, 2016, vol. 18, no. 27, s. 18063-18073. ISSN: 1463-9076.

FROLICH, K. - BULÁNEK, R. - FRÝDOVÁ, E. Interaction of CO probe molecules with Cu(+) in MCM-22 zeolite Microporous and Mesoporous Materials, 2014, vol. 186, no. March, s. 37-45. ISSN: 1387-1811.

AREAN, C. - DELGADO, M. - BULÁNEK, R. - FROLICH, K. Combined microcalorimetric and IR spectroscopic study on carbon dioxide adsorption in H-MCM-22 Applied Surface Science, 2014, vol. 316, no. October, s. 532-536. ISSN: 0169-4332.

FROLICH, K. - BULÁNEK, R. - FRÝDOVÁ, E. Energetic heterogeneity of Cu+-carbonyl complexes in Y zeolites: Kinetics of CO desorption studied by FTIR combined with CO adsorption microcalorimetry Microporous and Mesoporous Materials, 2013, vol. 171, no. N, s. 185-195. ISSN: 1387-1811.

FROLICH, K. - KOUDELKOVÁ, E. - FRÝDOVÁ, E. - BULÁNEK, R. The quantity of Cu+ ions forming isolated and bridged carbonyl complexes in FER zeolites determined by IR spectroscopy Vibrational Spectroscopy, 2012, vol. 58, no. January, s. 146-152. ISSN: 0924-2031.

BULÁNEK, R. - FROLICH, K. - FRÝDOVÁ, E. - ČIČMANEC, P. Study of adsorption sites heterogeneity in zeolites by means of coupled microcalorimetry with volumetry Journal of Thermal Analysis and Calorimetry, 2011, vol. 105, no. 2, s. 443-449. ISSN: 1388-6150.

BULÁNEK, R. - FROLICH, K. - ČIČMANEC, P. - NACHTIGALLOVA, D. - PULIDO, A. - NACHTIGALL, P. Combined Experimental and Theoretical Investigations of Heterogeneous Dual Cation Sites in Cu,M-FER Zeolites Journal of Physical Chemistry C, 2011, vol. 115, no. 27, s. 13312-13321. ISSN: 1932-7447.

ČIČMANEC, P. - BULÁNEK, R. - FROLICH, K. Thermodynamics of CO probe molecule adsorption on Cu-FER-zeolite comparison of TPD, FTIR, and microcalorimetry results Journal of Thermal Analysis and Calorimetry, 2011, vol. 105, no. 3, s. 837-844. ISSN: 1388-6150.

BULÁNEK, R. - FROLICH, K. - FRÝDOVÁ, E. - ČIČMANEC, P. Microcalorimetric and FTIR study of the adsorption of carbon dioxide on alkali-metal exchanged FER zeolites Topics in Catalysis, 2010, vol. 53, no. 19-20, s. 1349-1360. ISSN: 1022-5528.

AREÁN, C. - DELGADO, M. - FROLICH, K. - BULÁNEK, R. - PULIDO, A. - BIBILONI, G. - NACHTIGALL, P. Computational and FTIR Spectroscopic Studies on CO Adsorption on the Zeolites Na-ZSM-5 and K-ZSM-5: Evidence of Dual-cation Sites Journal of Physical Chemistry C, 2008, vol. 112, no. 12, s. 4658-4666. ISSN: 1932-7447.

NACHTIGALL, P. - PULIDO, A. - FROLICH, K. - BULÁNEK, R. Evidence of Heterogeneous Dual Cation Sites in Zeolites by Combined IR and DFT Investigation Studies in Surface Science and Catalysis, 2008, vol. 174, no. N, s. 1005-1008. ISSN: 0167-2991.

BULÁNEK, R. - FROLICH, K. - AREÁN, C. - NACHTIGALLOVÁ, D. - NACHTIGALL, P. Vibrational Dynamics of Small Molecules Adsorbed on Cation Sites in Zeolite Channel Systems: IR and DFT Investigation Studies in Surface Science and Catalysis, 2008, vol. 174, no. N, s. 869-872. ISSN: 0167-2991.

FROLICH, K. - BULÁNEK, R. - NACHTIGALL, P. Li+-carbonyl Spectra: Distribution of Cation Sites in FER. In Proceedings of 9th Pannonian International Symposium on Catalysis. Bratislava: Slovenská technická univezita v Bratislave, 2008. s. 62-68 s. ISBN 978-80-227-2923-9.

NACHTIGALL, P. - DELGADO, R. - FROLICH, K. - BULÁNEK, R. - PALOMINO, G. - BAUCA, L. - AREAN, C. Periodic Density Functional and FTIR Spectroscopic Studies on CO Adsorption on the Zeolite Na-FER Microporous and Mesoporous Materials, 2007, vol. 106, no. 1-3, s. 162-173. ISSN: 1387-1811.

NACHTIGALL, P. - FROLICH, K. - DROBNÁ, H. - BLUDSKÝ, O. - NACHTIGALLOVÁ, D. - BULÁNEK, R. FTIR and Theoretical Study of CO Interactions with Li+ Ions in Micro- and Mesoporous Matrices: Coordination and Localization of Li+ ions Journal of Physical Chemistry C, 2007, vol. 111, no. N, s. 11353-11362. ISSN: 1932-7447.

Projects

---

---

---

---

---

---

---

---