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Complexes of 2,6-Bis(5-alkyl-1,5-dimethyl-4,5-dihydro-1H-imidazol-4-on-2-yl)pyridine ligands. Synthesis, characterization and solvolytic stability
Authors: Drabina Pavel | Hanusek Jiří | Jirásko Robert | Sedlák Miloš
Year: 2006
Type of publication: článek v odborném periodiku
Name of source: Transition Metal Chemistry
Publisher name: Springer
Page from-to: 1052-1056
Titles:
Language Name Abstract Keywords
cze Komplexy 2,6-Bis(5-alkyl-1,5-dimethyl-4,5-dihydro-1H-imidazol-4-on-2-yl)pyridinových ligandů. Syntéza, charakterizace a solvolytická stabilita Byly připraveny nové 2,6-bis(5-alkyl-1,5-dimethyl-4,5-dihydro-1H-imidazol-4-on-2-yl)pyridiny a charakterizovány 1H-, 13C-NMR and elemenární analýzou. Tyto ligandy tvoří komplexy s FeCl2, které byly rovněž isolovány a charakterizovány elementární analýzou a MS. Dále byly stanoveny rychlostní konstanty kysele katalyzovaného rozpadutěchto komplexů. Komplexy, 2,6-Bis(5-alkyl-1,5-dimethyl-4,5-dihydro-1H-imidazol-4-on-2-yl)pyridiny, solvolytická stabilita
eng Complexes of 2,6-Bis(5-alkyl-1,5-dimethyl-4,5-dihydro-1H-imidazol-4-on-2-yl)pyridine ligands. Synthesis, characterization and solvolytic stability New 2,6-bis(5-alkyl-1,5-dimethyl-4,5-dihydro-1H-imidazol-4-on-2-yl)pyridines have been prepared and characterized by 1H-, 13C-NMR and elemental analysis. These ligands form complexes with FeCl2, which were isolated and characterized by elemental analysis and MS. By means of the kinetic stopped-flow method, the rate constants of acid catalyzed decomposition were determined. Complexes, 2,6-Bis(5-alkyl-1,5-dimethyl-4,5-dihydro-1H-imidazol-4-on-2-yl)pyridines, solvolytic stability

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