Publication detail

Synthesis and Complexation Properties of Substituted 2,2´-Bis(4-isopropyl-4-methyl-4,5-dihydro-1H-imidazol-5-ones

Authors: Sedlák Miloš | Drabina Pavel | Valenta Petr | Hanusek Jiří

Year: 2006

Type of publication: článek ve sborníku

Name of source: International Conference on Organic Chemistry ?Organic Chemistry Since Butlerov and Beilstein until Present?

Publisher name: Sankt-Petěrburgskij Gosudarstvenij Universitet

Place: Sankt Peterburg

Page from-to: 340-341

Titles:

Language	Name	Abstract	Keywords
cze	Syntéza a komplexační vlastnosti substituovaných 2,2´-bis(4-isopropyl-4-methyl-4,5-dihydro-1H-imidazol-5-onů	Připravili jsme 2,2´-bis(4-isopropyl-4-methyl-4,5-dihydro-1H-imidazol-5-ony a studovali jsme jejich komplexční vlastnosti se solemi Cu(II), Co(II) a Fe(III). Opticky čisté komplexy ligandu nesoucího methyl skupinu s CuCl2 a FeCl3 jsme použili jako katalyzátoty při Henryho nitroaldolizační reakci. Isolovaným produktem byl 2-nitro-1-(4-nitrofenyl)ethanol v celkovém výtěžku 49-93 %.
eng	Synthesis and Complexation Properties of Substituted 2,2´-Bis(4-isopropyl-4-methyl-4,5-dihydro-1H-imidazol-5-ones	We prepared 2,2´-bis(4-isopropyl-4-methyl-4,5-dihydro-1H-imidazol-5-ones and studied their complexation properties with Cu(II), Co(II) and Fe(III) cations. The optically pure complexes of the ligand carrying methyl group with CuCl2 and FeCl3 we used as catalysts in Henry nitroaldolisation reaction. The isolated product was 2-nitro-1-(4-nitrophenyl)ethanol in overall yields of 49-93 %.	Synthesis, Complexation Properties, 2,2´-Bis(4-isopropyl-4-methyl-4,5-dihydro-1H-imidazol-5-ones

Search