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Magnetically recoverable catalyst for Henry reaction based on Fe3O4@SiO2 nanoparticles
Authors: Sedlák Miloš | Bhosale Dattatry | Hanusek Jiří | Drabina Pavel
Year: 2015
Type of publication: ostatní - přednáška nebo poster
Page from-to: nestránkováno
Titles:
Language Name Abstract Keywords
eng Magnetically recoverable catalyst for Henry reaction based on Fe3O4@SiO2 nanoparticles The preparation and characterization of a heterogeneous recyclable catalyst based on Cu(II) complex of magnetic nanoparticles Fe3O4@SiO2 with (2R,5S)-5-isopropyl-5-methyl-2-(pyridine-2-yl)imidazolidine-4-one was described. Reactions of substituted aldehydes with nitromethane catalyzed by this catalyst provide high conversion (82 – 99%) and high enantioselectivity (73 – 94 % ee). Magnetically recoverable catalyst; Henry reaction; Fe3O4@SiO2 nanoparticles