Publikace detail

Synthesis of Ph2LSn(l-OH)Bu3SnCl. Trapping of monomeric triorganotin hydroxide Ph2LSnOH

Autoři: Dostál Libor | Taraba Jan | Jambor Roman

Rok: 2009

Druh publikace: článek v odborném periodiku

Název zdroje: Journal of Organometallic Chemistry

Strana od-do: 1251-1253

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	Syntéza Ph2LSn(l-OH)Bu3SnCl. Stabilizace monomerního triorganocíničitého hydroxidu Ph2LSnOH	Reakce triorganociničitého chloridu Ph2LSnCl (1), (L = 2,6-(t-BuOCH2)2C6H3) a (Bu3Sn)2O vedla k syntéze Ph2LSn(l-OH)Bu3SnCl (2).
eng	Synthesis of Ph2LSn(l-OH)Bu3SnCl. Trapping of monomeric triorganotin hydroxide Ph2LSnOH	The reaction of triorganotin(IV) compound Ph2LSnCl (1), (L = 2,6-(t-BuOCH2)2C6H3), with (Bu3Sn)2O resulted to the isolation of Ph2LSn(l-OH)Bu3SnCl (2), in which a monomeric triorganotin(IV) hydroxide Ph2LSnOH intermolecularly coordinates Bu3SnCl moiety. Compound 2 was characterized by combination of 1H, 13C and 119Sn NMR spectroscopy, ESI/MS, elemental analysis and X-ray diffraction.	Organotin compounds, Pincer ligands, NMR spectroscopy, Crystal structure

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