Publikace detail

The stannylene {2,6-(Me2NCH2)(2)C6H3} SnCl as a Ligand in Transition Metal Complexes of Palladium, Ruthenium, Rhodium

Autoři: Martincová Jana | Dostálová Romana | Dostál Libor | Růžička Aleš | Jambor Roman

Rok: 2009

Druh publikace: článek v odborném periodiku

Název zdroje: Organometallics

Název nakladatele: American Chemical Society

Místo vydání: Washington

Strana od-do: 4823-4828

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	Stannylen {2,6-(Me2NCH2)(2)C6H3} SnCl jako ligand v komplexech Pd, Ru a Rh	Byly připraveny komplexy přechodných kovů Ru, Rh a Pd a stanylenu {2,6-(Me2NCH2)(2)C6H3} SnCl .
eng	The stannylene {2,6-(Me2NCH2)(2)C6H3} SnCl as a Ligand in Transition Metal Complexes of Palladium, Ruthenium, Rhodium	The cleavage of the chloride bridge in the dimeric transition complexes [(η3-C3H5)Pd]2(μ-Cl)2, [(η6-benzene)RuCl]2(μ-Cl)2, [(η6-cymene)RuCl]2(μ-Cl)2, [(CΟ)3RuCl]2(μ-Cl)2, and [(CΟ)2Rh]2(μ-Cl)2 by heteroleptic LSnCl stannylene (L is a N,C,N-pincer ligand [2,6-(Me2NCH2)2C6H3]) resulted in the isolation of PdII-SnII, RuII-SnII, and RhI-SnII complexes [Pd(η3-C3H5)(LSnCl)Cl] (2), [Ru(η6-benzene)(LSnCl)Cl2] (3), [Ru(η6-cymene)(LSnCl)Cl2] (4), [Ru(CO)3(LSnCl)Cl2] (5), and [Rh-(CO)2(LSnCl)Cl] (6). All compounds were characterized by NMR and IR spectroscopy, and the structures of compounds 2 and 4 were determined by X-ray diffraction analysis. The structure of a rare monomeric RhII-SnII complex, [Rh(LSnCl)2Cl2] (7), the final decomposition product of RhI-SnII complex 6, is also reported.	stannylene, chelating ligand, transition metals complexes

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