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Publikace detail

Difluoro(eta5,eta5-propane-2,2-diyldicyclopentadienyl)titanium(IV)
Autoři: Erben Milan | Císařová Ivana | Vinklárek Jaromír | Picka Michal
Rok: 2005
Druh publikace: článek v odborném periodiku
Název zdroje: Acta Crystallographica Section E - Structure Reports Online
Název nakladatele: International Union of Crystallography
Strana od-do: m1266-m1268
Tituly:
Jazyk Název Abstrakt Klíčová slova
cze Difluoro(eta5,eta5-propane-2,2-diyldicyclopentadienyl)titanium(IV) In the title compound, [Ti(C13H14)F2], the coordination polyhedron around the Ti atom is a distorted tetrahedron defined by the centroids of the cyclopentadienyl rings and the two F atoms. The Ti?ring centroid (Cg) distances are 2.0558 (7) and 2.0567 (8) A° . The presence of a short carbon bridge linking the cyclopentadienyl rings constrains the Cg? Ti?Cg angle to a value of 121.50 (3)DEG. ansa-metalloceny, titan, mlekulová struktura
eng Difluoro(eta5,eta5-propane-2,2-diyldicyclopentadienyl)titanium(IV) In the title compound, [Ti(C13H14)F2], the coordination polyhedron around the Ti atom is a distorted tetrahedron defined by the centroids of the cyclopentadienyl rings and the two F atoms. The Ti?ring centroid (Cg) distances are 2.0558 (7) and 2.0567 (8) A° . The presence of a short carbon bridge linking the cyclopentadienyl rings constrains the Cg? Ti?Cg angle to a value of 121.50 (3)DEG. ansa-metallocenes, titanium, X-ray