Publikace detail

Reduktivní aminace cyklopentanonu: kinetická studie

Rok: 2005

Druh publikace: ostatní - přednáška nebo poster

Název zdroje: APROCHEM 2005

Název nakladatele: PCHE - PetroCHemEng

Místo vydání: Milovy - Sněžné n. M.

Strana od-do: 141-145

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	Reduktivní aminace cyklopentanonu: kinetická studie	The kinetics of heterogeneous catalytic reductive amination of cyclopentanone has been studied on a pilot plant PARR autoclave. N-cyclopentyliminocyclopentane was detected as the main intermediate in a reaction mixture. It was found that, at the given conditions, the main intermediate does not form the undesirable N,N-dicyclopentylamine but undergoes slow hydrolysis, and the desired product, cyclopentylamine, results in a good yield. Slight amounts of by-products such as cyclopentanole and N,N-dicyclopentylamine were obtained. The experimental data were confronted with the suggested kinetic model.
eng	Reductive amination of Cyclopentanone: Kinetic study	The kinetics of heterogeneous catalytic reductive amination of cyclopentanone has been studied on a pilot plant PARR autoclave. N-cyclopentyliminocyclopentane was detected as the main intermediate in a reaction mixture. It was found that, at the given conditions, the main intermediate does not form the undesirable N,N-dicyclopentylamine but undergoes slow hydrolysis, and the desired product, cyclopentylamine, results in a good yield. Slight amounts of by-products such as cyclopentanole and N,N-dicyclopentylamine were obtained. The experimental data were confronted with the suggested kinetic model.	Cyclopentanone; Cyclopentylamine; N-cyclopentyliminocyclopentane; Heterogeneous catalytic reductive amination; Kinetics

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