Publikace detail

1-[2-(N,N-dimethylaminomethyl)phenyl]-2,3,4,5-tetraphenylcyclopentadien-1-ol

Autoři: Erben Milan | Císařová Ivana | Dušek Michal | Vinklárek Jaromír

Rok: 2007

Druh publikace: článek v odborném periodiku

Název zdroje: Acta Crystallographica Section E - Structure Reports Online

Název nakladatele: International Union of Crystallography

Strana od-do: o577-o579

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	1-[2-(N,N-dimethylaminomethyl)fenyl]-2,3,4,5-tetraphenylcyclopentadien-1-ol	The crystal structure of the title compound, C38H33NO, shows that the OH group interacts with the N atom of the dimethylamino group via an intramolecular hydrogen bond, resulting in the formation of a seven-membered ring. The presence of this interaction, the poor nucleofugal properties of the hydroxy function and the particularly high steric hindrance decrease the ability of the OH group for substitution by other nucleophiles. The crystal packing exhibits no classical intermolecular hydrogen bonds.	molekulová struktura, vodíková vazba
eng	1-[2-(N,N-dimethylaminomethyl)phenyl]-2,3,4,5-tetraphenylcyclopentadien-1-ol	The crystal structure of the title compound, C38H33NO, shows that the OH group interacts with the N atom of the dimethylamino group via an intramolecular hydrogen bond, resulting in the formation of a seven-membered ring. The presence of this interaction, the poor nucleofugal properties of the hydroxy function and the particularly high steric hindrance decrease the ability of the OH group for substitution by other nucleophiles. The crystal packing exhibits no classical intermolecular hydrogen bonds.	X-ray structure, hydrogen bonding

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